مشخصات پژوهش

عنوان	Immobilization of Schiff base-Pd complex in mesoporous silica KIT-6 channels: A novel, green, recyclable, and highly versatile mesoporous catalyst for the carbon-carbon cross-coupling reaction
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Immobilization of Schiff base-Pd complex in mesoporous silica KIT-6 channels: A novel, green, recyclable, and highly versatile mesoporous catalyst for the carbon-carbon cross-coupling reaction
چکیده	In this study, we developed an efficient and novel nanocatalyst by immobilizing Schiff base-Pd complex inside mesoporous silica KIT-6 channels, which were successfully synthesized by using a simple procedure. The catalytic activity of KIT-6@Schiff base-Pd was investigated in the synthesis of a wide variety of biphenyl derivatives. The N2 adsorption–desorption isotherms indicated the excellent Brunauer–Emmett–Teller surface area for KIT-6@Schiff base-Pd of 121.65 m2/g. The chemical and physical properties of raw and modified samples (KIT-6@Schiff base-Pd) were characterized based on Fourier transform-infrared spectra, thermogravimetric analysis, energy-dispersive X-ray spectroscopy, N2 adsorption–desorption, scanning electron microscopy, X-ray elemental mapping, and X-ray diffraction analyses. We found that the synthesized catalyst could be recovered and reused up to four times.
پژوهشگران	منظر اکبری (نفر اول)، آرش قربانی چقامارانی (نفر دوم)، حمید آقاوندی (نفر سوم)، محسن نیکورزم (نفر چهارم)، بهمن طهماسبی (نفر پنجم)