مشخصات پژوهش

عنوان	Synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using UiO66(Zr)-N(CH2PO3H2)2 as a catalyst†
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Picolinates, cooperative vinylogous anomeric-based oxidation, MOF
چکیده	The anomeric effect highlights the significant influence of the functional group and reaction conditions on oxidation–reduction. This article successfully investigates the anomeric effect in the synthesis of picolinate and picolinic acid derivatives through a multi-component reaction involving 2-oxopropanoic acid or ethyl 2-oxopropanoate, ammonium acetate, malononitrile, and various aldehydes. To facilitate this process, we employed UiO-66(Zr)-N(CH2PO3H2)2 as a novel nanoporous heterogeneous catalyst. The inclusion of phosphorous acid tags on the UiO-66(Zr)-N(CH2PO3H2)2 offers the potential for synthesizing picolinates at ambient temperature.
پژوهشگران	سعید بابایی (نفر اول)، حسن سپهرمنصوری (نفر دوم)، محمود زارعی (نفر سوم)، محمدعلی زلفی گل (نفر چهارم)، مجتبی حسینی فرد (نفر پنجم)