مشخصات پژوهش

صفحه نخست /Homoselective Synthesis of ...
عنوان Homoselective Synthesis of tetrazoles and chemoselective oxidation of sulfides using Ni(II)-Schiff base complex stabilized on 3-dimensional mesoporous KIT-6 surface as a recyclable nanocatalyst
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Chemoselective oxidation of sulfides; Homoselective synthesis of tetrazole; Mesoporous KIT-6; Reusable nanocatalyst
چکیده Mesoporous silica with thick expanded walls, open porosity, and excellent thermal stability is a relatively new structure known as KIT-6. In this study, KIT-6 mesoporous was synthesized by using pluronic surfactant P123 as a modulator in an acidic environment. The synthesized KIT-6 was then modified by 3-chloropropyltrimethoxysilane (3-CPTMS) and finally, the nickel metal complex was fixed on the modified mesoporous KIT-6. IR, BET, XRD, EDS, SEM, AAS, and TGA methods were employed to examine the as-prepared catalyst. The proposed catalyst was then used for selective sulfides oxidation and preparation of tetrazole derivatives. The synthesized catalyst was found to be efficient and practical as it produced organic compounds in proper TOF and TON amounts, demonstrating the catalyst's practicality and efficiency. © 2023
پژوهشگران منظر اکبری (نفر اول)، محسن نیکورزم (نفر دوم)، بهمن طهماسبی (نفر سوم)، آرش قربانی چقامارانی (نفر چهارم)