مشخصات پژوهش

صفحه نخست /Application of Zr‑MOFs based ...
عنوان Application of Zr‑MOFs based copper complex in synthesis of pyrazolo[3, 4‑b]pyridine‑5‑carbonitriles via anomeric‑based oxidation
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها -
چکیده In this research article, Zr‑MOFs based copper complex as a novel heterogeneous and porous catalyst was designed and prepared. The structure of catalyst has verified by various techniques such as FT‑IR, XRD, SEM, N2 adsorption–desorption isotherms (BET), EDS, SEM‑elemental mapping, TG and DTG analysis. UiO‑66‑NH2/TCT/2‑amino‑Py@Cu(OAc)2 was used as an efficient catalyst in the synthesis of pyrazolo[3,4‑b]pyridine‑5‑carbonitrile derivatives. The aromatization of titled molecules is performed via a cooperative vinylogous anomeric‑based oxidation both under air and inert atmospheres. The unique properties of the presented method are short reaction time, high yield, reusability of catalyst, synthesis of desired product under mild and green condition.
پژوهشگران الهام توکلی (نفر اول)، حسن سپهرمنصوری (نفر دوم)، محمود زارعی (نفر سوم)، محمدعلی زلفی گل (نفر چهارم)، اردشیر خزایی (نفر پنجم)، محمدعلی اصحابی (نفر ششم به بعد)