عنوان
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Synthesis and Application of Novel Magnetic Glycoluril Tetrakis(Methylene Phosphorous Acid) as a Nano Biological Catalyst for the Preparation of Nicotinonitriles via a Cooperative Vinylogous Anomeric-Based Oxidation
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Anomeric effect; anomericbased oxidation; biological catalyst; diphenyl nicotinonitrile; Fe3O4@GTMPA; Glycoluril tetrakis(methylene phosphorous acid); nanomagnetic catalyst
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چکیده
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Herein, we synthesized biological magnetic glycoluril tetrakis(methylene phosphorous acid) as a new heterogeneous nano-catalyst. The magnetic nano-catalyst Fe3O4@GTMPA was used for the synthesis of diphenyl nicotinonitrile derivatives by multi-component reaction of wide spread aldehydes, acetophenones, ammonium acetate, and 3-(1H-indol-3-yl)-3-oxopropanenitrile in the solvent-free conditions at 110 C. The final step of reaction mechanism was preceded via a cooperative vinylogous anomericbased oxidation (CVABO) as green and convenient approach.
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پژوهشگران
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بشیرالله دانش یار (نفر اول)، حسن سپهرمنصوری (نفر دوم)، محمود زارعی (نفر سوم)، محمدعلی زلفی گل (نفر چهارم)، محمدعلی اصحابی (نفر پنجم)، یانلانگ لی (نفر ششم به بعد)
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