مشخصات پژوهش

صفحه نخست /Dissipative vibrational model ...
عنوان Dissipative vibrational model for chiral recognition in olfaction
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Decoherence Dissipative model of olfaction Double well Potential
چکیده We examine the olfactory discrimination of left- and right-handed enantiomers of chiral odorants based on the odorant-mediated electron transport from a donor to an acceptor of the olfactory receptors embodied in a biological environment. The chiral odorant is effectively described by an asymmetric double-well potential whose minima are associated to the left- and right-handed enantiomers. The introduced asymmetry is considered an overall measure of chiral interactions. The biological environment is conveniently modeled as a bath of harmonic oscillators. The resulting spin-boson model is adapted by a polaron transformation to derive the corresponding Born-Markov master equation with which we obtain the elastic and inelastic electron tunneling rates. We show that the inelastic tunneling through left- and right-handed enantiomers occurs with different rates. The discrimination mechanism depends on the ratio of tunneling frequency to localization frequency
پژوهشگران آرش تیرانداز (نفر اول)، فرهاد طاهر قهرمانی (نفر دوم)، افشین شفیعی (نفر سوم)