مشخصات پژوهش

صفحه نخست /Emergence of molecular ...
عنوان Emergence of molecular chirality due to chiral interactions in a biological environment
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Biomolecular Homochirality Chiral Interactions Decoherence Theory
چکیده We explore the interplay between tunneling process and chiral interactions in the discrimination of chiral states for an ensemble of molecules in a biological environment. Each molecule is described by an asymmetric double-well potential and the environment is modeled as a bath of harmonic oscillators. We carefully analyze different time-scales appearing in the resulting master equation at both weak- and strong-coupling limits. The corresponding results are accompanied by a set of coupled differential equations characterizing optical activity of the molecules. We show that, at the weak-coupling limit, chiral interactions prohibit the coherent racemization induced by decoherence effects and thus preserve the initial chiral state. At the strong-coupling limit, considering the memory effects of the environment, Markovian behavior is observed at long times
پژوهشگران آرش تیرانداز (نفر اول)، فرهاد طاهر قهرمانی (نفر دوم)، افشین شفیعی (نفر سوم)