عنوان
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Emergence of molecular chirality due to chiral interactions in a biological environment
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Biomolecular Homochirality Chiral Interactions Decoherence Theory
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چکیده
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We explore the interplay between tunneling process and chiral interactions in the discrimination of chiral states for an ensemble of molecules in a biological environment. Each molecule is described by an asymmetric double-well potential and the environment is modeled as a bath of harmonic oscillators. We carefully analyze different time-scales appearing in the resulting master equation at both weak- and strong-coupling limits. The corresponding results are accompanied by a set of coupled differential equations characterizing optical activity of the molecules. We show that, at the weak-coupling limit, chiral interactions prohibit the coherent racemization induced by decoherence effects and thus preserve the initial chiral state. At the strong-coupling limit, considering the memory effects of the environment, Markovian behavior is observed at long times
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پژوهشگران
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آرش تیرانداز (نفر اول)، فرهاد طاهر قهرمانی (نفر دوم)، افشین شفیعی (نفر سوم)
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