مشخصات پژوهش

عنوان	Electrochemical synthesis of new quinone-imines with assisted of 4-ethynylaniline and para-toluidine as nucleophile
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Electrochemical oxidation Para-toluidine 4-ethynylaniline Cyclic voltammetry Catechol derivatives
چکیده	Electrochemical oxidation of 3 and 4 substituted catechols in the presence of 4-ethynylaniline and para-toluidine as a nucleophile in acetonitrile/ sodium acetate 0.15 M (30/70) solution has been carried out in detail with employing the cyclic voltammetry and controlled potential coulometry methods. The results show that the obenzoquinones derived from these catechols participate in Michael type reaction with these nucleophiles to form the corresponding new p-quinone imines. We derived some new p-quinone-imines derivatives with good yields based on the electrochemical oxidation in the controlled potential situation, without toxic reagents and solvents, at the carbon electrode, and in an undivided cell.
پژوهشگران	مریم مهردادیان (نفر اول)، صادق خزل پور (نفر دوم)، آمنه امانی (نفر سوم)