عنوان
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Applications of Selectfluor® for the oxidation of Sulfides, urazoles and alcohols under the solvent-free conditions
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Selectfluor®; oxidation; urazoles; alcohols; sulfides
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چکیده
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Selectfluor ® acts as a safe and efficient reagent for the oxidation of urazoles, alcohols and also sulfides via releasing the electrophile F under the solvent-free conditions. In room temperature, this reagent cannot oxidize the substrates alone and requires KBr as the catalyst. In the proposed mechanism, Selectfluor ® converts the Br - to the Br-F and the lone-pair electron of substrates attack to Br-F to perform the oxidation reaction. This procedure offers some advantages; for example short reaction time, simple work-up, good yield and matching with some green chemistry approaches.
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پژوهشگران
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غلام عباس چهاردولی (نفر اول)، شادپور ملک پور (نفر سوم)
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