مشخصات پژوهش

صفحه نخست /Poly(sulfonamide-thiourea) ...
عنوان Poly(sulfonamide-thiourea) grafted γ-Fe2O3@talc as a green catalyst for the synthesis of substituted tetrahydropyridines
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها -Fe2O3/ talc, poly(sulfonamide-thiourea) (PBST), tetrahydropyridine
چکیده Herein, we aim to study the role of template and polymers on the synthesis of tetrahydropyridine scaffolds, novel composite (γ-Fe2O3@talc@PBST) was synthesized from immobilization of poly (sulfonamide-thiourea) on the surface of γ-Fe2O3@talc. Poly(sulfonamide-thiourea) (PBST) was synthesized for the first time as a polydentate nitrogen donor ligand and combined with the γ-Fe2O3@talc as a novel organic-inorganic catalyst in order to construct of tetrahydropyridine derivatives from the reaction of aromatic aldehydes, anilines and 1,3-dicarbonyl compounds in good to excellent yield. Additionally, γ-Fe2O3@talc@PBST has shown a very good reusability up to six consecutive recycle tests and its activity has not changed significantly. The prepared γ-Fe2O3@talc@PBST has an excellent catalytic activity, which is due to the combined effect of Brønsted acidity and high density functional groups.
پژوهشگران شیوا ظفری (نفر اول)، رامین قربانی واقعی (نفر دوم)، صدیقه علوی نیا (نفر سوم)