مشخصات پژوهش

صفحه نخست /A new palladium heterogeneous ...
عنوان A new palladium heterogeneous complex (Pd-Gu@BOEH): chemoselective, phosphine-free and practical nanocatalyst in carbon–carbon cross-coupling reaction
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Boehmite nanoparticles · Palladium · C–C coupling · Heck reaction · Suzuki reaction
چکیده Herein, boehmite nanoparticles were synthesized via combination of Al(NO3)3·9H2O and NaOH in aqueous solution. This nanomaterial converted to Pd-Gu@BOEH in several sequences. Pd-Gu@BOEH was used as efcient and recoverable nanocatalyst for the chemoselective C–C band formation such as Mizoroki–Heck and Suzuki–Miyaura reactions without any phosphine ligands or inert atmosphere. This catalyst has been characterized by several analyses such as EDS, WDX, SEM, XRD, FT-IR, TEM, TGA, AAS and BET. Also, obtained products from C–C coupling reactions were identifed by NMR spectroscopy and their melting points. This catalyst was recycled in described reactions without palladium leaching. The reused catalyst was characterized by EDS, WDX, XRD, FT-IR and AAS analysis, which showed good stability during reaction process
پژوهشگران فریبا جعفری (نفر اول)، آرش قربانی چقامارانی (نفر دوم)، ندا حسن زاده (نفر سوم)