عنوان
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H2O2 as a green and environmentally benign reagent for the oxidation of sulfides in the presence of {[K.18-Crown-6]X3}n (X= Br, I) compared with some other organic tribromides
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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H2O2; {K.18-Crown-6]Br3}n; {K.18-Crown-6]I3}n; oxidation; sulfides; sulfoxides.
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چکیده
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In the presence of {[K.18-Crown-6]X3}n (X= Br, I)-as interesting trihalide reagents, organic sulfides were oxidized to their corresponding sulfoxides using H2O2 as a green reagent. {[K.18-Crown-6]X3}n activates H2O2 via in situ generation of HOX and variously substituted sulfides were selectively transformed into the corresponding sulfoxides. We compared the obtained results of {[K.18-Crown-6]X3}n with some other organic tribromides. Unexpectedly, in most cases, the results were similar.
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پژوهشگران
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محسن رسولی (نفر اول)، محمدعلی زلفی گل (نفر دوم)، محمد حسین مسلمین (نفر سوم)، راضیه موهبت (نفر چهارم)، غلامعباس چهاردولی (نفر پنجم)
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