مشخصات پژوهش

صفحه نخست /Study of molecular ...
عنوان Study of molecular interactions in binary mixtures containing 2-propanol, 1, 3-diaminopropane, and 2, 5-dimethoxytetrahydrofuran using macroscopic properties of solutions at 81.5 kPa and different temperatures
نوع پژوهش مقاله ارائه شده کنفرانسی
کلیدواژه‌ها Binary mixtures,Density, Excess molar volumes, Refractive index, Molecular interactions
چکیده Densities, and refractive indices , of binary mixtures consisting of 2-propanol, 1, 3-diaminopropane, and 2, 5-dimethoxytetrahydrofuran have been measured for the whole range of composition at temperatures of (298.15, 308.15, 318.15, and 328.15) K in ambient pressure (81.5 kPa). Excess molar volumes, Partial excess molar volumes, refractive index deviations , excess thermal expansion coefficient and isothermal coefficient of pressure excess molar enthalpy for mixtures were derived.and fo polynomial equation. The effect of temperature on the excess molar volumes and refractive index deviations are discussed in terms of molecular interaction between unlike molecules. Positive deviation from ideal state were recorded for excess volume in mixture of 1, 3-Diaminopropane + 2, 5-Dimethoxytetrahydrofuran and 2-Propanol + 2, 5-Dimethoxytetra-hydrofuran solution. However in mixture of 2-Propanol and 1, 3-Diaminopropane negative deviation in the high composition of 1, 3-Diaminopropane varies to positive in the dominated mole fraction of alcohol which was analyzed to interpret the molecular interactions.
پژوهشگران خاطره خانلرزاده (نفر اول)، حسین ایلوخانی (نفر دوم)