عنوان
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Friedel–Crafts alkylation of 4-hydroxycoumarin over silica-bonded 1,4-diaza-bicyclo[2.2.2] octane-sulfonic acid chloride as nanostructured heterogeneous catalyst
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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nanostructured catalyst, heterogeneous, silica-bonded 1,4-diaza-bicyclo[2.2.2]octane-sulfonic acid chloride (SBDBSAC), bis-coumarin, solvent free.
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چکیده
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Abstract: A novel nanostructured heterogeneous catalyst, namely silica-bonded 1,4-diaza-bicyclo[2.2.2]octane-sulfonic acid chloride (SBDBSAC), has been synthesized and fully characterized by several techniques, including Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), differential thermal gravimetric (DTG), scanning electron microscope (SEM), and energy dispersive X-ray analysis (EDX). Afterward, the nanostructured catalyst was utilized as an efficient catalyst for the synthesis of bis-coumarin derivatives by the condensation reaction of arylaldehydes with 4-hydroxycoumarin at 70 °C under solvent-free conditions.
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پژوهشگران
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احسان نوروزی زاده بنا (نفر اول)، سید احمد رضا موسوی زارع (نفر دوم)، عبدالکریم زارع (نفر چهارم)، محمود زارعی (نفر پنجم)
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