مشخصات پژوهش

عنوان	Novel nano molten salt tetra‐2,3‐pyridiniumporphyrazinato‐oxovanadium tricyanomethanide as a vanadium surface‐free phthalocyanine catalyst: Application to Strecker synthesis of α‐aminonitrile derivatives
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	molten salt, nano tetra‐2,3‐pyridiniumporphyrazinato‐oxo‐vanadium tricyanomethanide, phthalocyanine, Strecker synthesis, α‐aminonitrile
چکیده	Efficient and recyclable novel nano tetra‐2,3‐pyridiniumporphyrazinato‐oxovanadium tricyanomethanide, {[VO(TPPA)][C(CN)3]4}, as a vanadium surface‐free phthalocyanine‐based molten salt catalyst was successfully designed, produced and used for the Strecker synthesis of α‐aminonitrile derivatives through a one‐pot three‐component reaction between aromatic aldehydes, trimethylsilyl cyanide and aniline derivatives under neat conditions at 50 °C. This catalyst was well characterized using Fourier transform infrared, UV–visible, X‐ray photoelectron and energydispersive X‐ray spectroscopies, X‐ray diffraction, scanning and high‐resolution transmission electron microscopies, inductively coupled plasma mass spectrometry and thermogravimetric analysis. The catalyst can be simply recovered and reused several times without significant loss of catalytic activity.
پژوهشگران	سعید باقری (نفر اول)، محمدعلی زلفی گل (نفر دوم)، ملیحه السادات صفایی (نفر سوم)، دیگو آلونسو (نفر چهارم)، عباس خشنود (نفر پنجم)