مشخصات پژوهش

عنوان	Kinetic study of electrochemically induced Michael reactions of o-benzoquinones with 2-acetylcyclohexanone and 2-acetylcyclopentanone
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	o-benzoquinones; cyclic voltammetry; 2-acetylcyclohexanone; digital simulation; EC mechanism; Michael reaction; homogeneous rate constants
چکیده	The reaction of electrochemically generated o-benzoquinones (2a-f) as Michael acceptors with 2-acetylcyclohexanone (ACH) and 2-acetylcyclopentanone (ACP), as nucleophiles has been studied in various pHs using cyclic voltammetry. The results indicate that the participation of o-benzoquinones (2a-f) in the Michael reaction with acetylcyclohexanone (ACH) to form the corresponding catechol derivatives (4a-f). Based on an EC mechanism, the homogeneous rate constants were estimated by comparing the experimental cyclic voltammetric responses with the digital simulated results.
پژوهشگران	محمد علیمرادی (نفر اول)، محمد رفیعی (نفر سوم)