مشخصات پژوهش

صفحه نخست /Electrochemical Oxidation of ...
عنوان Electrochemical Oxidation of Sulfinic Acids: Efficient Oxidative Synthesis of Diaryl Disulfones
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Electrochemical Oxidation of Sulfinic Acids: Efficient Oxidative Synthesis of Diaryl Disulfones
چکیده Electrochemical oxidation of sulfinic acids has been studied in aqueous solutions using cyclic voltammetry, controlled-potential coulometry, chronoamperometry and chronocoulometry methods. The results indicate that the oxidation of sulfinic acids is an irreversible one-electron transfer process. Our data also show that the electrogenerated sulfonyl radicals undergo a dimerization reaction to form disulfone derivatives. The present work has led to the development of a facile and environmentally friendly electrochemical method for the synthesis of diphenyl disulfone derivatives.
پژوهشگران داود نعمت الهی (نفر اول)، مهسا جودکی (نفر دوم)، صادق خزل پور (نفر سوم)، فیروزه پولادی (نفر چهارم)