عنوان
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Electrochemical Oxidation of Sulfinic Acids: Efficient Oxidative Synthesis of Diaryl Disulfones
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Electrochemical Oxidation of Sulfinic Acids: Efficient Oxidative Synthesis of Diaryl Disulfones
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چکیده
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Electrochemical oxidation of sulfinic acids has been studied in aqueous solutions using cyclic voltammetry, controlled-potential coulometry, chronoamperometry and chronocoulometry methods. The results indicate that the oxidation of sulfinic acids is an irreversible one-electron transfer process. Our data also show that the electrogenerated sulfonyl radicals undergo a dimerization reaction to form disulfone derivatives. The present work has led to the development of a facile and environmentally friendly electrochemical method for the synthesis of diphenyl disulfone derivatives.
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پژوهشگران
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داود نعمت الهی (نفر اول)، مهسا جودکی (نفر دوم)، صادق خزل پور (نفر سوم)، فیروزه پولادی (نفر چهارم)
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