عنوان
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Cyclic Voltammetric Study of the Oxidation of Catechols in the Presence of Cyanide Ion
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Catechol, Cyclic voltammetry, Digital simulation, Cyanide ion, o-Dihydroxybenzonitrile
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چکیده
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Electrochemical oxidation of catechols has been studied in the presence of cyanide ion as nucleophile in aqueous solution, by means of cyclic voltammetry and controlled-potential coulometry. The results indicate that the participation of catechols in the Michael reaction with cyanide ion to form the corresponding o-dihydroxybenzonitrile. Based on an EC mechanism, the homogeneous rate constants were estimated by comparing the experimental cyclic voltammetric responses with the digital simulated results.
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پژوهشگران
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داود نعمت الهی (نفر اول)، محمد علیمرادی (نفر دوم)، س واقیف حسین (نفر سوم)
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