مشخصات پژوهش

صفحه نخست /[4,4′-Bipyridine]-1,1′-diium ...
عنوان [4,4′-Bipyridine]-1,1′-diium tricyanomethanide as a nanostructured molten salt and its catalytic application in the synthesis of tetrahydrobenzo[b]pyrans, amido and aminoalkyl naphthol derivatives
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Bifunctional nano structure molten salt [4,4′-bipyridine]-1,1′-diium tricyanomethanide Tetrahydrobenzo[b]pyrans Amidoalkyl naphthol Aminoalkyl naphthol Solvent-free conditions
چکیده An efficient process for the synthesis of tetrahydrobenzo[b]pyrans derivatives was attained via the reaction of dimedone, various aldehydes and malononnitrile using [4,4′-Bipyridine]-1,1′-diium tricyanomethanide {[4,4′- BPyH][C(CN)3]2} as a green mild nano structure molten salt catalyst under solvent-free conditions at room temperature. To further investigation on catalytic properties of {[4,4′-BPyH][C(CN)3]2}, itwas used in the synthesis of amido and aminoalkyl naphthol derivatives under solvent-free conditions at 75 °C. {[4,4′-BPyH][C(CN)3]2} has advantages such as cleaner reaction profile, benign characters, cost effectiveness, reusability of the catalysts and being in agreement with the green chemistry protocols
پژوهشگران محمدعلی زلفی گل (نفر اول)، میثم یاری (نفر دوم)، سعید باقری (نفر سوم)