مشخصات پژوهش

صفحه نخست /Catalytic application of ...
عنوان Catalytic application of N,2-dibromo-6-chloro-3,4- dihydro-2H-benzo[e][1,2,4]thiadiazine-7-sulfonamide 1,1-dioxide as a new catalyst for the synthesis of 9-aryl- 1,8-dioxo-octahydroxanthenes under neutral media
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها N,2-dibromo-6-chloro-3,4- dihydro-2H-benzo[e][1,2,4]thiadiazine-7-sulfonamide 1,1-dioxide ,9-aryl- 1,8-dioxo-octahydroxanthenes
چکیده A new N-bromo sulfonamide reagent, namely N,2-dibromo-6-chloro-3,4- dihydro-2H-benzo[e][1,2,4]thiadiazine-7-sulfonamide 1,1-dioxide, was synthesized and used as a new and highly efficient catalyst for the preparation of 9-aryl-1,8-dioxooctahydroxanthene derivatives by the condensation reaction of dimedone (5,5- dimethylcyclohexane-1,3-dione) and various arylaldehydes. Mechanistically, it is interesting that in situ generation of the Br? ion from the catalyst is successfully catalyzed by this reaction under neutral media.
پژوهشگران اردشیر خزایی (نفر اول)، فاطمه عباسی (نفر دوم)، سید احمد رضا موسوی زارع (نفر سوم)