عنوان
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Salting-out Effect of NaCl on the Liquid–Liquid Equilibrium of Water + Acetone + HMIMPF6 Ionic Liquid
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نوع پژوهش
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مقاله ارائه شده کنفرانسی
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کلیدواژهها
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Liquid-liquid equilibrium, Ionic liquids, Separation factor, Salting-out
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چکیده
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The salting-out effect of NaCl on the liquid-liquid equilibrium (LLE) of the ternary water + acetone + 1-hexyl-3-methylimidazolium hexafluorophosphate (HMIMPF6) system was studied at 298.2 K and under ambient pressure. The distribution coefficient of acetone between ionic liquid/aqueous phases increases with its concentration, both in salt-free and in the presence of salt. Adding a 5 wt% (based on initial water mass) NaCl leads to an average enhancement of about 46% in distribution coefficient; however, this criterion decreases to some extent with 10 wt% of this salt due to an increase in mutual solubility of HMIMPF6 and water.
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پژوهشگران
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جواد صاین (نفر اول)، مرجان محمدی سراب بادیه (نفر دوم)، مهدی نوروزی (نفر سوم)
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