عنوان
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Regioselective and facile oxidative thiocyanation of anilines and indoles with trans-3,5‐dihydroperoxy-3,5‐dimethyl‐1,2‐dioxolane
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Trans-3,5‐dihydroperoxy‐3,5‐dimethyl‐1,2‐dioxolane; DHPODMDO; sodium thiocyanate; thiocyanation; anilines; indoles.
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چکیده
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Oxidative potential of trans‐3,5‐dihydroperoxy‐3,5‐dimethyl‐1,2‐dioxolane (DHPODMDO) has been explored in the facile thiocyanation of anilines and indoles through the efficient and in situ generation of SCN+ ion from sodium thiocyanate. The reactions proceed with regioselectivity under mild conditions at room temperature to afford the respective thiocyanate derivatives in excellent yields and low reaction times.
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پژوهشگران
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داود آذری فر (نفر اول)، مریم گلباغی (نفر دوم)، مهتاب پیر ویسیان (نفر سوم)، زهره نجمی نژاد (نفر چهارم)
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