عنوان
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A very useful and mild method for the deoxygenation of sulfoxide to sulfide with silica bromide as heterogeneous promoter
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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silica bromide; sulfoxides; sulfides; deoxygenation; heterogeneous
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چکیده
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Silica bromide (SB) as heterogeneous reagent and promoter is prepared from reaction of silica gel with PBr3 as a non-hydroscopic, filterable, cheap, and stable yellowish powder that can be stored for months. The results show that the SB is suitable and efficient reagent for deoxygenation of sulfoxides to the corresponding sulfides under mild conditions at room temperature. The easy availability of this reagent makes this simple procedure attractive and a practical alternative to the existing methods.
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پژوهشگران
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فرج الله محنازاده (نفر اول)، حجت ویسی (نفر دوم)، علیرضا سدرپوشان سدرپوشان (نفر سوم)، محمدعلی زلفی گل (نفر چهارم)، فرشته گل محمد (نفر پنجم)، مجید هاشمی (نفر ششم به بعد)، صبا همتی (نفر ششم به بعد)
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