عنوان
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Moisture and air-stable, robust phosphine mono–ylide palladacycle precatalyst: A simple and highly efficient system for Mizoroki-Heck reactions
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Palladacycle phosphine mono-ylide complex, Non-symmetric phosphorus ylides, Mizoroki-Heck coupling reaction, Low Pd loadings, Aerobic conditions
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چکیده
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[(P^C)PdCl2] palladacycle phosphine mono-ylide complex, where P^C chelate ligand = Ph2PCH2PPh2CHC(O)C6H4C6H5, have been identified as efficient catalyst system for the Mizoroki-Heck cross-coupling reaction of a variety of aryl bromides including electron-rich, and electron deficient substituents with two aryl- and alkyl-olefins in moderate to excellent yields, in relatively low Pd loadings and under aerobic conditions.
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پژوهشگران
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سیدجواد سیدزاده صابونچی (نفر اول)، محسن احمدی (نفر دوم)، طیبه عزیزی (نفر سوم)، محمد پناهی مهر (نفر چهارم)
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