مشخصات پژوهش

صفحه نخست /Electrochemical Synthesis of ...
عنوان Electrochemical Synthesis of Sulfonamide Derivatives Based on the Oxidation of 2,5-Diethoxy-4-Morpholinoaniline in the Presence of Arylsulfinic Acids
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها 'Sulfonamide Derivatives' '2,5'Diethoxy-4-Morpholinoaniline'' Arylsulfinic'
چکیده Some new sulfonamide derivatives were synthesized in aqueous solutions via anodic oxidation of 2,5- diethoxy-4-morpholinoaniline in the presence of arylsulfinic acids using a commercial carbon anode. In addition, the formation mechanism of the products was discussed. The obtained data show that the electrogenerated quinone diimine undergoes a Michael-type addition reaction with arylsulfinic acids to yield the respective sulfonamide derivatives. In this work, two different types of products (mono- and disulfone derivatives) in the same precursor could be isolated just by controlling the exerted potentials.
پژوهشگران هادی بیگی نژاد (نفر اول)، داود نعمت الهی (نفر دوم)