عنوان
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Electrochemical Synthesis of Sulfonamide Derivatives Based on the Oxidation of 2,5-Diethoxy-4-Morpholinoaniline in the Presence of Arylsulfinic Acids
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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'Sulfonamide Derivatives' '2,5'Diethoxy-4-Morpholinoaniline'' Arylsulfinic'
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چکیده
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Some new sulfonamide derivatives were synthesized in aqueous solutions via anodic oxidation of 2,5- diethoxy-4-morpholinoaniline in the presence of arylsulfinic acids using a commercial carbon anode. In addition, the formation mechanism of the products was discussed. The obtained data show that the electrogenerated quinone diimine undergoes a Michael-type addition reaction with arylsulfinic acids to yield the respective sulfonamide derivatives. In this work, two different types of products (mono- and disulfone derivatives) in the same precursor could be isolated just by controlling the exerted potentials.
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پژوهشگران
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هادی بیگی نژاد (نفر اول)، داود نعمت الهی (نفر دوم)
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