مشخصات پژوهش

عنوان	Electrosynthesis of hydroquinonethioethers using electrochemical oxidation of hydroquinone in the presence of thiouracil derivatives
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	'hydroquinonethioethers''electrochemical' ' 'hydroquinone' 'thiouracil derivatives
چکیده	Electrochemical oxidation of hydroquinone (1a) has been studied in the presence of 6-methyl-2- thiouracil (3a) and 6-propyl-2-thiouracil (3b) as nucleophiles in a DMF/buffer mixture, using cyclic voltammetry and controlled-potential coulometry. The results indicated that the p-quinone (2a) derived from 1a participates in a 1,4-Michael addition reaction with the thiouracil derivatives (3a–b) to form the corresponding hydroquinonethioether derivatives (6a–6b). The electrosynthesis of these compounds (6a–b) has been successfully performed on carbon rod electrodes in an undivided cell in good yield and purity.  2014
پژوهشگران	محسن عامری (نفر اول)، علیرضا اصغری (نفر دوم)، علی عموزاده (نفر سوم)، حسن دانشی نژاد (نفر چهارم)، داود نعمت الهی (نفر پنجم)