مشخصات پژوهش

صفحه نخست /Electrochemical Synthesis of ...
عنوان Electrochemical Synthesis of Aminoquinones through Oxidative Coupling of 4-tert-Butylcatechol and Benzenamines
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Electrochemical Synthesis' 'Aminoquinones' ' '4-tert-Butylcatechol'
چکیده The electrochemical oxidation of 4-tert-butylcatechol in the presence of a series of benzenamines has been evaluated in aqueous solution by means of cyclic voltammetry and controlled-potential coulometry. Results indicate that 4-tert-butylcatechol undergoes a two-electron oxidation at the surface of electrode to 4-tert-butylquinone followed by Michael addition reaction with benzenamine. This study has established the formation of aminoquinones as final products via the ECE mechanism. This procedure would be a good candidate for synthesis of aminoquinones in one-pot process, green conditions and good purity.
پژوهشگران داود نعمت الهی (نفر اول)، بهاره فیضی برناجی (نفر دوم)، حمید صالح زاده (نفر سوم)، فهیمه ورمقانی (نفر چهارم)