The present study investigated the wear and electrochemical behaviors of CrN/AlCrN multilayered coatings post-annealed at 300, 450, and 600◦C temperatures. The cathodic arc evaporation technique has been utilized to deposit the coatings. Scanning electron microscope, field emission SEM, energy-dispersive X-ray, grazing incidence X-ray diffraction, and Rockwell-C indenter methods were used to characterize the coatings and to investigate the interdiffusion between the multilayered CrN/AlCrN and the H13 base metal.