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Title A GREEN AND EFFICIENT SOLVENT- AND CATALYST-FREE ULTRASONIC DIBENZYLATION PROCEDURE
Type JournalPaper
Keywords N,N-dibenzylation, aromatic amines, ultrasound irradiation, solvent and catalyst-free reactions, room temperature.
Abstract A greener improvement was achieved for the synthesis of diverse N,N-dibenzylated compounds from the reaction of various aromatic amines with benzyl bromide using the ultrasound irradiation in solvent- and catalyst-free conditions. The dibenzylation reactions were carried out in different solvents and solvent-free conditions under ultrasound irradiation at various temperatures. The yields were very low in all applied solvents, while in the solvent-free condition and at room temperature, the yields were excellent. Due to obtaining the high reaction yields, the catalyst was not used.
Researchers davood habibi (Second Researcher), (Third Researcher), (First Researcher)