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Title Preparation and application of a Deep Eutectic Solvent based on triphenylphosphonium as a capable and new catalyst for the synthesis of benzopyranophenazine
Type Presentation
Keywords Deep Eutectic Solvent, Synthesis, benzo[a]pyrano[2,3‐c] phenazines, Henna‐based compounds
Abstract At the beginning of our century, Abbott’s group published a few papers that triggered research in the area we call today Deep Eutectic Solvents (DES) [1]. An alternative family of ionic liquids (IL), DES, is rapidly emerging. DES is a fluid generally composed of ionic compounds hydrogen-bond acceptors (HBA) and hydrogen-bond donors (HBD) (often cheap and derived from safe components) that are capable of self-association to form a eutectic mixture. Two salts with high melting points are mixed and form at eutectic with a melting point lower than that of each component [2].In this project, a cheap, simple, and non-toxic method was considered for the synthesis of benzo [a]pyrano[2,3‐ c] phenazines derivatives. the structure and properties of the DES catalyst were investigated by FT-IR, TGA/DTA, DSC, Density, eutectic point, and 1HNMR. Advantages provided by this study include reaction in solvent-free conditions (reduction of contamination), short reaction time, high productivity, easy recycling and separation of the catalyst, as well as high selectivity
Researchers Hadis Goudarzi (Fourth Researcher), maryam mahmoudiani gilan (Third Researcher), Arezo Monem (First Researcher), davood habibi (Second Researcher)