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Title Application of ammonium acetate as a dual rule reagent-catalyst in synthesis of new symmetrical terpyridines
Type JournalPaper
Keywords Ammonium acetate Indole Terpyridines Vinylogous anomeric-based oxidation
Abstract Herein, we present a green, efficient and simple synthetic route to the new symmetrical terpyridines by using ammonium acetate (NH4OAc) as catalytically active reagent. Various techniques including Fourier transform infrared (FT-IR) spectroscopy, 1H NMR, 13C NMR and Mass analysis have been applied for characterization of synthesized molecules. Moreover, a cooperative vinylogous anomeric-based oxidation pathway is suggested for the aromatization of titled molecules both under air and inert atmospheres.
Researchers Yanlong Gu (Fourth Researcher), Meysam Yarie (Third Researcher), ma z (Second Researcher), MORTEZA TORABI (First Researcher)