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Title
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Two-Phase Electrochemical Generation of Aryldiazonium Salts: Application in Electrogenerated Copper-Catalyzed Sandmeyer Reactions
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Type
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JournalPaper
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Keywords
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Two-Phase Aryldiazonium Salt Copper-Catalyzed Sandmeyer Reactions
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Abstract
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The electrochemical generation of aryldiazonium salts from nitroarenes in a twophase system (ethyl acetate/water) was reported for the first time. Some compounds including azo, azosulfone, and arylazides were prepared in good yields with good purity. Cathodically generated aryldiazoniums and anodically produced copper(Ι) ions were used to perform Sandmeyer reactions. To improve the method, an H-type self-driving cell equipped with a Zn rod as an anode was introduced and used for two-phase aryldiazonium production
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Researchers
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Davood Nematollahi (Fourth Researcher), (Third Researcher), (Second Researcher), (First Researcher)
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