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Abstract
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1,10-Phenanthrolin-1-ium trinitromethanide (1,10-PHTNM) as a novel nano molten slat with Y-aromatic counter ion was synthesized and fully characterized by using various techniques such as FT-IR, 1HNMR, 13CNMR, mass, TGA, DTG, XRD, SEM and TEM. A series of organic compounds include 1,4-dihydropyrano [2,3-c]pyrazoles, tetrahydrobenzo[b]pyran, pyrano[4,3-b]pyrans, bispyrazole, 1H-pyrazolo[3,4-b]quinolones, hexahydroacridine- 1,8-diones and methylenebis(3-hydroxy-5,5-dimethylcyclohex- 2-enones) were synthesized in the presence of 1,10-PHTNM as a novel and efficient proton sponge nano molten slat catalyst. According to the results of FT-IR, 1HNMR, 13CNMR, mass spectrum of 1,10-PHTNM and due to high electron charge density and none bonded repulsion of lone pair electrons between two nitrogen atoms (peri-effect), this catalyst is a type of proton sponge.
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