Research Info

Home /Synthesis and Application of ...
Title Synthesis and Application of a Novel Ionically Tagged Polymer as a Nano- Heterogeneous Catalystfor Synthesis of N-Heterocycle Spiropyrans under Mild and Green Conditions
Type Presentation
Keywords Polymers, pyrrolidonium. polymeric ionic liquids PILs
Abstract Nowadays, ionically tagged polymers including cations such as imidazolium, pyrrolidonium, pyridinium and anions such as tetrafluoroborate, hexafluorophosphate, triflates incorrectly have been called polymeric ionic liquids PILs [1] .Organic and biological based solid acids are one of the most applicable compounds which have been used for acid-promoted processes and chemical methodologies. Solid acids have received great attention as general materials for a variety of chemical processes because of their reasonable properties such as nonmetallic, nontoxic, with no generated hazardous waste, reusability and high turnover [2]. Recently, application of solid acids with sulfonic acids tags as catalysts comprehensively reviewed [3]. The research and application of various multi-SO3H functionalized solid acids are interesting due to their nano structures, Brønsted acidic and environmentally friendly, good candidates for replacing of conventional solid acids, which could be used as a catalyst and reagent [5]. Spiro compounds as drug candidates are target molecules for pharmaceutical investigations. The unpleasant effects of oxidative stress on human health have become a serious issue. Herein, a novel ionically tagged polymer was synthesized and used as an efficient and reusable catalyst for the synthesis of spiropyran derivatives
Researchers ma z (Fourth Researcher), (Third Researcher), (Second Researcher), Hassan Sepehrmansourie (First Researcher)