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Title
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One-pot electrochemical synthesis of highly symmetric and conjugated coumarin derivative
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Type
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JournalPaper
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Keywords
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Electrochemical synthesis · 4-Hydroxy-6,7-dimethylcoumarin · Cyclic voltammetry · Hydrolysis reaction
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Abstract
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A facile and one pot electrochemical synthesis of disubstituted hydroquinone generated from the electrochemical oxidation of 4-1-(4-(4-hydroxyphenyl)piperazin-1-yl)ethanone (1) in the presence of 4-hydroxy-6,7-dimethylcoumarin (3) has been reported. The results revealed that p-quinone imine derived from oxidation of (1) participate in Michael addition reactions with 3 and followed by a hydrolysis reaction attain to the highly symmetric and conjugated coumarin derivative. We derived a new product in good yield based on controlled potential electrochemical oxidation at carbon electrode in a divided cell.
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Researchers
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Davood Nematollahi (Second Researcher), Amaneh Amani (First Researcher)
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