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Title
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Cu(II)-Schiff base covalently anchored to MIL-125(Ti)-NH2 as heterogeneous catalyst for oxidation reactions
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Type
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JournalPaper
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Keywords
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heterogeneous catalysis; metal-organic frameworks: Cu(II) Schiff-base complex; tert-butylhydroperoxyde
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Abstract
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MIL-125(Ti)-NH2 has been modified by reaction of salicylaldehyde with the terephthalate amino groups to form a salicylideneimine that act as ligands of Cu2+. The success of the postsynthetic modification was assessed by FTIR spectroscopy of the MIL-125(Ti)-NH2-Sal-Cu and by analysis by 1H NMR spectroscopy of the organic linkers upon dissolution of MIL-125(Ti)-NH2- Sal-Cu. In comparison with parent MIL-125(Ti)-NH2 and MIL-125(Ti)-NH2-Sal, that exhibit a poor activity, the presence of the Cu-Schiff base complex in MIL-125(Ti)-NH2-Sal-Cu catalyst
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Researchers
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hermenegildo carsia (Not In First Six Researchers), Ramin Ghorbani-Vaghei (Not In First Six Researchers), Davood Azarifar (Not In First Six Researchers), merceds alvaro (Fifth Researcher), (Fourth Researcher), seargio navalon (Third Researcher), andrea santiago (Second Researcher), (First Researcher)
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