|
Title
|
Cu(II)-Schiff base covalently anchored to MIL-125(Ti)-NH2 as heterogeneous catalyst for oxidation reactions
|
|
Type
|
JournalPaper
|
|
Keywords
|
heterogeneous catalysis; metal-organic frameworks: Cu(II) Schiff-base complex; tert-butylhydroperoxyde
|
|
Abstract
|
MIL-125(Ti)-NH2 has been modified by reaction of salicylaldehyde with the terephthalate amino groups to form a salicylideneimine that act as ligands of Cu2+. The success of the postsynthetic modification was assessed by FTIR spectroscopy of the MIL-125(Ti)-NH2-Sal-Cu and by analysis by 1H NMR spectroscopy of the organic linkers upon dissolution of MIL-125(Ti)-NH2- Sal-Cu. In comparison with parent MIL-125(Ti)-NH2 and MIL-125(Ti)-NH2-Sal, that exhibit a poor activity, the presence of the Cu-Schiff base complex in MIL-125(Ti)-NH2-Sal-Cu catalyst
|
|
Researchers
|
hermenegildo carsia (Not In First Six Researchers), Davood Azarifar (Not In First Six Researchers), merceds alvaro (Fifth Researcher), (Fourth Researcher), seargio navalon (Third Researcher), andrea santiago (Second Researcher), (First Researcher)
|