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Title
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Synthesis of Novel Nanostructured Pyrazine Molten Salt and its Application in the Synthesis of Pyridine derivatives
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Type
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Presentation
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Keywords
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Nanostructured Pyrazine Molten Salt Pyridine derivatives Anomeric Based of Oxidation mechanism.
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Abstract
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Molten salts and ionic liquids are both liquids mainly composed of ions. ILs and MSs are defined as those fused salts with a melting point less than 100 °C, with salts with higher melting points mentioned to as molten salts [1]. Also, the anomeric effect is a fundamental concept, which includes an interaction between the lone pair electrons of heteroatom and the anti-bonding orbitals of adjacent bonds and can control reaction mechanism. In this regard, a new term "anomeric based oxidation" is introduced for unusual hydride releasing from crabon [2], [3].Therefore we decided to design and synthesize a novel, task-specific MSs for synthesis of 2- Amino-3,5-dicarbonitrile-6-sulfanylpyridine derivatives via Anomeric Based of Oxidation mechanism.
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Researchers
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Asiye Asgari (Not In First Six Researchers), Yadollah Bayat (Not In First Six Researchers), Avat Taherpour (Not In First Six Researchers), (Not In First Six Researchers), (Fifth Researcher), (Fourth Researcher), (Third Researcher), Maliheh Safaiee (Second Researcher), ma z (First Researcher)
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