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Title
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A Regioselective and Convergent Paired Electrochemical Synthesis of N,N′-Diphenyl-3-sulfonyl-[1,1′-biphenyl]-4,4′-diamines
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Type
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JournalPaper
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Keywords
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regioselective synthesis, electrosynthesis, Michael acceptors, cyclic voltammetry, convergent paired synthesis, N,N′-diphenylbenzidine
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Abstract
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A regioselective synthesis of N,N′-diphenyl-3-sulfonyl-[1,1′- biphenyl]-4,4′-diamine derivatives is carried out by anodic oxidation of N,N′-diphenylbenzidine in the presence of sulfinic acids as nucleophiles via a convergent paired electrochemical process. The sulfonylated aromatic amine products are obtained under mild reaction conditions with high yields, high current efficiency and atom economy.
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Researchers
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Farzad Nikpour (Third Researcher), Davood Nematollahi (Second Researcher), mahnaz Sharafi-Kolkeshvandi (First Researcher)
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