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Title
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Direct oxidative conversion of benzylhalides, -amines, -alcohols and arylaldehydes to nitriles with trans-3,5-dihydroperoxy-3,5- dimethyl-1,2-dioxolane activated by NH4Br
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Type
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JournalPaper
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Keywords
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Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2- ,dioxolane , DHPDMDO ,Oxidation , Nitrile , Amine , Halide , Alcohol , Aldehyde
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Abstract
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A simple and efficient oxidative conversion of benzyl derivatives of halides, amines, alcohols, and aldehydes into corresponding nitriles is described using trans- 3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane in the presence of NH4Br. The reactions proceeded smoothly at room temperature to afford the products in high-to-excellent yields.
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Researchers
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(Second Researcher), Davood Azarifar (First Researcher)
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