Research Info

Home /C(sp2)–C(sp2) cross coupling ...
Title C(sp2)–C(sp2) cross coupling reaction catalyzed by a palladacycle phosphine complex: A simple and sustainable protocol in aqueous media
Type JournalPaper
Keywords Palladium complex; Heck cross-coupling reaction; low catalyst loading; aerobic conditions
Abstract The Heck reactions of various aryl halides with olefins using {[Ph2PCH2PPh2CH=C(O)(C10H7)] PdCl2} as efficient catalyst has been investigated. The mononuclear palladacycle complex showed excellent activity in aqueous phase including the C(sp2)–C(sp2) cross coupling reactions. The advantages of the protocol are high yields, short reaction time, a cleaner reaction profile and notable simplicity.
Researchers (Second Researcher), seyyed javad seyyadzadeh sabounchei (First Researcher)