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Title
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Catalyst‑free and selective oxidation of pyridine derivatives and tertiary amines to corresponding N‑oxides with 1,2‑diphenyl‑1,1,2,2‑tetrahydroperoxyethane
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Type
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JournalPaper
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Keywords
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Oxidation · Pyridine-N-oxide · 1,2-Diphenyl- 1,1,2,2-tetrahydroperoxyethane · Catalyst-free
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Abstract
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The catalyst-free oxidation of various pyridine derivatives and tertiary amines to their corresponding N-oxides with 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane as an efficient oxidant has been developed. The methodology proved to tolerate a number of functional groups. The reactions proceeded smoothly under solvent-free and mild conditions at room temperature. All the products were easily extracted from the reaction mixtures in excellent yields.
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Researchers
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(Second Researcher), Davood Azarifar (First Researcher)
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