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Title
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Regioselective and facile oxidative thiocyanation of anilines and indoles with trans-3,5‐dihydroperoxy-3,5‐dimethyl‐1,2‐dioxolane
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Type
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JournalPaper
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Keywords
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Trans-3,5‐dihydroperoxy‐3,5‐dimethyl‐1,2‐dioxolane; DHPODMDO; sodium thiocyanate; thiocyanation; anilines; indoles.
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Abstract
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Oxidative potential of trans‐3,5‐dihydroperoxy‐3,5‐dimethyl‐1,2‐dioxolane (DHPODMDO) has been explored in the facile thiocyanation of anilines and indoles through the efficient and in situ generation of SCN+ ion from sodium thiocyanate. The reactions proceed with regioselectivity under mild conditions at room temperature to afford the respective thiocyanate derivatives in excellent yields and low reaction times.
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Researchers
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Mahtab Pirveisian (Third Researcher), (Fourth Researcher), (Second Researcher), Davood Azarifar (First Researcher)
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