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Title
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Programming of microwave-assisted synthesis of new isophthalatederivatives using ZrOCl2as a catalyst under solvent-free condition byexperimental design
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Type
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JournalPaper
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Keywords
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MicrowaveDesign of experimentOptimizationIsophthalateZrOCl2
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Abstract
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tIn this investigation, isophthalate derivatives were prepared by the reaction of isophthaloyl dichloridewith various alcohol derivatives using ZrOCl2as an efficient, green and a heterogeneous catalyst undermicrowave irradiation and solvent- free condition. Optimization of the reaction condition was studiedby the response surface method (Box Behnken Design (BBD)) with three replicates at a central point fordeveloping a second order model. Predicting response values using the obtained model were in a goodaccordance with the experimental results. Clean reaction, easy workup procedure, the reusability of thecatalyst, short reaction times and high yields were some advantages of this work.
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Researchers
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ahmad reza moosavi-zare (Not In First Six Researchers), (Fifth Researcher), jaber yousefi-seyf (Fourth Researcher), Ardeshir Khazaei (Second Researcher), (Third Researcher), ma z (First Researcher)
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