tImidazole-based ionic liquid-stabilized on silica coated Fe3O4magnetic nano particles [nano-Fe3O4@SiO2@(CH2)3-Imidazole-SO3H]Cl as a novel heterogeneous acidic catalyst was designed,synthesized and fully characterized by FT-IR, thermo gravimetric analysis (TGA), differential thermalanalysis (DTA), energy-dispersive x-ray spectroscopy (EDX), X-ray diffraction patterns (XRD), scanningelectron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM),Brunauer–Emmett–Teller (BET) and inductively coupled plasma (ICP) analysis. The nano-structuredorgano solid catalyst as a novel, mild and full-fledged catalyst was used for the cascade synthesis of1,8-dioxo-octahydroxanthene derivatives by the condensation reaction between dimedone and variousaldehydes at 80◦C under solvent-free conditions. Similarly, dihydropyrano[2,3-c]pyrazole derivativeswere synthesized by the one-pot three-component condensation reaction of aldehydes, malononitrileand 3-methyl-1-phenyl-2-pyrazoline-5-one under solvent-free conditions at room temperature. To theknowledge of our science, this is the main investigation on the synthesis of [nano-Fe3O4@SiO2@(CH2)3-Imidazole-SO3H]Cl as a worthy heterogeneous nano magnetic solid acid for acid catalyzed organicreactions.
