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Roya Karamian

Roya Karamian

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId: 8372362500
HIndex:
Faculty: Faculty of Science
Address:
Phone: 081-38247880

Research

Title
Synthesis, cadmium sensing ability and biological activities of a pyrrole-based macrocyclic Schiff base fluorescent ligand: DFT studies
Type
JournalPaper
Keywords
Schiff base
Year
2024
Journal Journal of Molecular Structure
DOI
Researchers Hassan Keypour ، ، ، Roya Karamian ،

Abstract

A novel turn-on fluorescent sensor was designed for cadmium detection and synthesized by the condensation reaction of a prepared dialdehyde with diethylenetriamine, and characterized by FT-IR, UV–visible, 1 HNMR, Mass spectra, and elemental analyses. According to the fluorescent findings, an approximately 3-fold enhancement of the emission intensity of L toward Cd 2+ Antioxidant Fluorescent ligand DFT make significant changes (LOD=2.7× 10 the band gap (E 9 ions was observed at 430 nm, while 18 other metal ions did not M). DFT calculations confirmed the experimental results. Lowering g ) and increasing the electrophilicity index ( ω ) indicated that charge transfer is responsible for the enhancement of emission intensity of L when binding to Cd 2+ . The sensor (L) and its complexes exhibited significant antioxidant potency. Furthermore, [CdL] demonstrated much more extensive antibacterial activity against Staphylococcus aureus, Pseudomonas aeruginosa, and Escherichia coli, among other evaluated compounds.