2025 : 4 : 21

Ramin Ghorbani-Vaghei

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId: 55665692200
HIndex:
Faculty: Faculty of Chemistry and Petroleum Sciences
Address:
Phone: 988118254707

Research

Title
CuI nanoparticles-immobilized on a hybrid material composed of IRMOF-3 and a sulfonamide-based porous organic polymer as an efficient nanocatalyst for one-pot synthesis of 2,4-diaryl-quinolines
Type
JournalPaper
Keywords
IRMOF-3, MOF-polymer composite, Nano porous materials, Copper iodide, Quinoline
Year
2023
Journal RSC Advances
DOI
Researchers ، ، Ramin Ghorbani-Vaghei

Abstract

As a significant class of synthetic and natural products with multiple biological activities, Quinolines are used in medical and electronic devices. Herein, a novel method is presented in order to synthesize 2,4-diarylquinoline derivatives via a simple one-pot multicomponent reaction between phenylacetylenes, aniline derivatives and aldehydes in CH3CN using IRMOF-3/PSTA/Cu. Notably, Polymer/MOF is stabilized through a reaction between a sulfonamide-triazine-based porous organic polymer [poly(sulfonamide-triazine)](PSTA) and an amino-functionalized zinc metal-organic framework (IRMOF-3). Next, the prepared nanocomposites (IRMOF-3/PSTA) are modified using copper iodide nanoparticles (CuI NPs). Overall, the high product yields, facile recovery of nanocatalysts, short reaction times and broad substrate range make this process environmentally friendly, practical and economically justifiable.