In this paper, we aim at synthesizing a new nanocomposite material in which bentonite acts as a nucleation site for MgFe2O4 nanoparticle precipitation in the attendance of an external magnetic field (MgFe2O4@Bentonite). Moreover, poly (guanidine- sulfonamide) as a novel kind of polysulfonamide was immobilized on the surface of the prepared support (MgFe2O4@Bentonite@PGSA). Finally, an efficient and environmentally friendly catalyst (containing nontoxic polysulfonamide, copper, and MgFe2O4@Bentonite) was prepared via anchoring a copper ion on the surface of MgFe2O4@Bentonite@PGSAMNPs.The synergic effect of MgFe2O4 magnetic nanoparticles (MNPs), Bentonite, PGSA, and copper species was observed while conducting the control reactions. The synthesized Bentonite@MgFe2O4@PGSA/Cu, which was characterized using energy-dispersive X-ray spectroscopy (EDAX), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and Fourier-transform infrared (FT-IR) spectroscopy, was applied as a highly efficient heterogeneous catalyst in order to synthesize 1,4-dihydropyrano[2,3-c] pyrazole yielding up to 98% at 10 minutes. Excessive yield, quick reaction time, using water solvent, turning waste to wealth, and recyclability are the important advantages of the present work.
