2025/12/20

Ramin Ghorbani-Vaghei

Academic rank: Professor
ORCID:
Education: PhD.
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E-mail: ghorbani [at] basu.ac.ir
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Phone: 988118254707
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Research

Title
Cu(II)-Schiff base covalently anchored to MIL-125(Ti)-NH2 as heterogeneous catalyst for oxidation reactions
Type
JournalPaper
Keywords
heterogeneous catalysis; metal-organic frameworks: Cu(II) Schiff-base complex; tert-butylhydroperoxyde
Year
2018
Journal JOURNAL OF COLLOID AND INTERFACE SCIENCE
DOI
Researchers ، andrea santiago ، seargio navalon ، ، merceds alvaro ، Davood Azarifar ، Ramin Ghorbani-Vaghei ، hermenegildo carsia

Abstract

MIL-125(Ti)-NH2 has been modified by reaction of salicylaldehyde with the terephthalate amino groups to form a salicylideneimine that act as ligands of Cu2+. The success of the postsynthetic modification was assessed by FTIR spectroscopy of the MIL-125(Ti)-NH2-Sal-Cu and by analysis by 1H NMR spectroscopy of the organic linkers upon dissolution of MIL-125(Ti)-NH2- Sal-Cu. In comparison with parent MIL-125(Ti)-NH2 and MIL-125(Ti)-NH2-Sal, that exhibit a poor activity, the presence of the Cu-Schiff base complex in MIL-125(Ti)-NH2-Sal-Cu catalyst