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ma z

Academic rank: Professor
ORCID:
Education: PhD.
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HIndex:
Faculty: Faculty of Chemistry and Petroleum Sciences
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Research

Title
1,10-Phenanthrolin-1-ium trinitromethanide (1,10-PHTNM) as a Nano Molten Salt Catalyst with Y-Aromatic Counter ion: Applications for the Synthesis of Organic Compounds
Type
Presentation
Keywords
1,10-Phenanthrolin-1-ium trinitromethanide, Novel nano molten slat
Year
2019
Researchers ، ، ma z ، Yadollah Bayat ، Asiye Asgari

Abstract

1,10-Phenanthrolin-1-ium trinitromethanide (1,10-PHTNM) as a novel nano molten slat with Y-aromatic counter ion was synthesized and fully characterized by using various techniques such as FT-IR, 1H NMR, 13C NMR, mass, TGA, DTG, XRD, SEM and TEM. A series of organic compounds including 1,4-dihydropyrano[2,3-c]pyrazoles, tetrahydrobenzo[ b]pyran, pyrano[4,3-b]pyrans, bispyrazole, 1H-pyrazolo[3,4-b]quinolones, hexahydroacridine‐ 1,8‐diones and methylenebis(3‐hydroxy‐5,5‐dimethylcyclohex‐2‐enones) were synthesized in the presence of described 1,10-PHTNM as a novel and efficient proton sponge nano molten slat catalyst. These heterocyclces are considerable attention of organic chemists due to their broad range of pharmaceutical and biological properties containing arisugacins, antimultidrug- resistant, anti-inflammatory [1], photodynamic therapy, inhibitors of human Chk1 kinase, spasmolytic, anti-filarial agents [2].