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ma z

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId:
HIndex:
Faculty: Faculty of Chemistry and Petroleum Sciences
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Research

Title
Synthesis and application of a novel nanomagnetic catalyst with Cl[DABCO-NO2]C(NO2)3 tags in the preparation of pyrazolo[3,4-b]pyridines via anomeric based oxidation
Type
JournalPaper
Keywords
Pyrazolo[3,4-b]pyridine  Nanomagnetic catalyst  Fe2O3@SiO2(CH2)3- Cl[DABCO-NO2]C(NO2)3  Solvent-free  Anomeric-based oxidation
Year
2018
Journal RESEARCH ON CHEMICAL INTERMEDIATES
DOI
Researchers ، ma z ، Ardeshir Khazaei ، diogo alonoso ، Abbas Khoshnood ، yadollah bayat ، Asiye Asgari

Abstract

A novel nanomagnetic catalyst with Cl[DABCO-NO2]C(NO2)3 tags was designed, synthesized and fully characterized by several techniques such as Fourier transform infrared spectroscopy, energy-dispersive X-ray spectroscopy, elemental mapping analysis, thermogravimetric analysis, derivative thermal gravimetric, powder X-ray diffraction patterns, field scanning electron microscopy, high resolution transmission electron microscopy, physical adsorption and desorption of N2 isotherms (BET) and vibrating sample magnetometer. The synthesized nanomagnetic particles were used as an efficient and recyclable catalyst for the one-pot three component condensation reaction of 3-methyl-1-phenyl-1H-pyrazol-5-amine or 3-methyl-1Hpyrazol- 5-amine, aryl aldehydes and malononitrile for the synthesis of pyrazolo[3,4- b]-pyridine derivatives under neat conditions.